Ketones and Aldehydes
Topic
Synthesis from primary alcohols I: PCC and PDC oxidation
Synthesis from primary alcohols II: Swern oxidation
Synthesis from primary alcohols III: Dess-Martin Periodinane (DMP) Oxidation
Synthesis from acid halides
Synthesis from esters
Synthesis from nitriles
Synthesis from alkynes
Synthesis from benzylic and allylic oxidation
Synthesis of ketones from Friedel-Crafts acylation
Ketone and aldehyde hydration
Acetal formation
Thioacetal formation
Imine formation
Enamine formation
Oxime formation
Hydrazone formation
Reductive amination
Reduction to alcohols
Reduction to alkanes I: Wolff-Kishner reduction
Reduction to alkanes II: Clemmensen reduction
Reduction to alkanes III: reduction of thioacetals
Oxidation of aldehydes to carboxylic acids
Addition of Grignard reagents
Addition of organolithium reagents
Cyanohydrin formation
Olefination I: Wittig reaction
Olefination II: stabilized Wittig reaction
Olefination III: Horner-Wadsworth-Emmons (HWE) reaction
Baeyer-Villiger oxidation
1,4-Conjugate additions to alpha, beta-unsaturated carbonyls